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郑州轻工业大学硕士生导师基本情况一览表姓名
邢宇
职称
副教授
学科/专业学位类别
化学工程与技术
研究方向
煤化工(工业催化)、电池材料、食品分析
1.导师基本情况
长期从事费托合成催化剂的研究。揭示了合成气选择加氢一步制取环己酮和烃类的催化技术,拓展了费托合成用复合氧化物催化剂新领域;钝化法构筑了费托新型FTO铁催化剂用复合固体碱载体,在2MPa合成气高总压下实现无助剂时C2=-C4=低碳烯烃选择性翻一番;建立了同位素示踪、绝对干燥实验、原位红外、在线质谱四联用失活研究方法,探明了关键组分氟流失对催化剂活性影响机制,为解决困扰学术界、工业界长达数十年的重整催化剂失活难题奠定了理论基础。
近年来主持国家自然科学基金项目2项;获河南省教育厅科技成果奖一等奖1项;发表SCI论文二十余篇;授权发明专利7件;承担本科生“物理化学”、“化学简史”和研究生“智能材料(Smart Materials)”等教学工作。
1996年获得河南大学化学工程专业工学学士学位。
1999年获得辽宁石油化工大学化学工艺专业工学硕士学位。
1999至2003年,在中国石油化工股份有限公司上海石油化工研究院从事沸石分子筛材料和芳烃烷基转移催化剂的科研工作。
2003至2008年在美国康涅狄格大学(University of Connecticut)留学,师从无机材料化学与催化专家Steven L. Suib教授,获化学专业博士学位。
2008年在美国西弗吉尼亚大学(West Virginia University)化学工程系从事钴系催化材料和费托合成法制取液体燃料的博士后(Postdoctoral Fellow)研究工作。
2009年至今,被郑州轻工业学院引进,在该校材料与化学工程学院、河南省表界面科学重点实验室工作,副教授职称,校聘教授岗位。省高校青年骨干教师。省青科协理事。研究方向包括煤化工(工业催化)、电池材料、食品分析。
2.代表性成果
Selected Publications(代表性论文)
1). Xing, Yu*, Gaopeng Jia, Zhenxin Liu, Shaoming Fang, Chenxi Zhao, Xuehui Guo, Steven L. Suib. Development of Highly Selective Support for CO Hydrogenation to Light Olefins with Partially Passivated Iron Catalysts, ChemCatChem, 2019, 11: 3187-3199.(Outside front cover article)
2)Xing, Yu*;Zhao,C;Jia,G;Fang,S;Liu,Z.(2018) Coprecipitated Fe/K/spinel nanocomposites for Fischer-Tropsch to lower olefins. J Nanopart Res 20: 202. https://doi.org/10.1007/s11051-018-4304-5
3) Liu, Zhenxin; Wu, Depeng; Guo, Xuehui; Fang, Shaoming; Wang, Lizhen; Xing, Yu*; Suib, Steven L.Robust Macroscopic 3D Sponges of Manganese Oxide Molecular Sieves. Chemistry - A European Journal2017, 23, 16213-16218.(Outside front cover article)
4)Xing, Yu*; Guo, Xuehui; Wu, Depeng; Liu, Zhenxin; Fang, Shaoming; Suib, Steven L.Construction of macroscopic 3D foams of metastable manganese oxides via a mild templating route: Effects of atmosphere and calcinations, Journal of Alloys and Compounds2017, 719, 22-29.
5)Xing, Yu*; Liu, Zhenxin; Wu, Depeng; Guo, Xuehui; Qu, Xiongwei; Fang, Shaoming; Suib, Steven L.Self-assembly synthesis of Mn3O4 hierarchical micro/nano architectures as supercapacitor electrodes, Journal of Materials Science: Materials in Electronics2017, 28, 12004-12014.
6)Liu, Zhenxin; Wu, Depeng; Xing, Yu*; Guo, Xuehui; Fang, Shaoming. Effect of in-situ sulfur poisoning on zinc-containing spinel-supported cobalt COhydrogenation catalyst, Applied Catalysis, A: General, 2016, 514, 164-172.
7)Liu, Zhenxin; Xue, Yingying; Wu, Depeng; Xing, Yu*; Fang, Shaoming. Effects of water addition on CO hydrogenation over zinc-containing spinel-supported cobalt catalyst, Catalysis Letters, 2015, 145(11): 1941-1947.
8)Liu, Zhenxin; Xing, Yu*; Fang, Shaoming; Qu, Xiongwei; Wu, Depeng; Zhang, Aiqin; Xu, Bei. Low temperature self-assembled synthesis of hexagonal plate-shape Mn3O43D hierarchical architectures and their application in electrochemical capacitors, RSC Advances, 2015, 5(68): 54867-54872.
9)Liu, Zhenxin; Xing, Yu*; Fang, Shaoming; Qu, Xiongwei. Facile synthesis of γ-MnOOH nanotubes and their application in electrochemical capacitors,Journal of Materials Science: Materials in Electronics, 2015, 26(8): 5975-5979.
10)Liu, Zhenxin; Xing, Yu*; Xue, Yingying; Wu, Depeng; Fang, Shaoming. Synthesis, characterization, and Fischer-Tropsch performance of cobalt/zinc aluminate nanocomposites via a facile and corrosion-free coprecipitation route,Journal ofNanoparticle Research, 2015, 17(2): 1-11.
11)Xing, Yu*; Liu, Zhenxin; Xue, Yingying; Wu, Depeng; Fang, Shaoming. Variation Trends of CO Hydrogenation Performance of (Al)-O-(Zn) Supported Cobalt Nanocomposites: Effects of Gradual Doping with Zn-O Lewis Base,Catalysis Letters,2016, 146(3): 682-691.
12)Liu, Zhenxin; Xu, Bei; Xing, Yu*; Li, Jingjing; Zhang, Linsen; Wang, Lizhen; Fang, Shaoming. Determination of the relationship between particle size and electrochemical performance of uncoated LiFePO4materials, Journal of Nanoparticle Research, 2015, 17(3): 1-12.
13)Liu, Zhenxin; Li, Jingjing; Xing, Yu*; Wang, Lizhen; Fang, Shaoming; Xu, Bei; Qu, Xiongwei. LiFePO4/C composites derived from precipitated FePO4precursor: effects of mixingprocesses, Ionics, 2014, 20(11): 1511-1516.
14) Xing,Yu;Khare Gyanesh P.;Suib,Steven L.Deactivation of Pt/F-KL Zeolite-type Naphtha Reforming Catalysts: in-situ IR and on-line Mass Spectrometry Studies of Fluorine Loss, Applied Catalysis A-General, 2011, 399, 179-183.
15) Xing, Y.; Liu, Z.; Couttenye, R.A.; Willis, W.S.; Suib, S.L.; Fanson, P.T.; Hirata, H.; Ibe,M.Processing of hydrocarbons in anAC discharge nonthermal plasma reactor: An approachto generate reducing agents for on-board automotiveexhaustgas cleaningJournal of Catalysis, 2008, 253, 28-36.
16) Liu, Z.; Xing, Y.; Chen, C., Zhao, L.,Suib,S.L. “Framework doping of indium in manganese oxide nanomaterials: Synthesis, characterization and electrocatalytic reduction of oxygen” Chemistry of Materials,2008,20, 2069-2071.
17) Xing, Y.; Liu, Z.; Gomez,S.; Suib,S.L.Tuning of texture and structure of copper-containing nanocomposite oxide materialsJournal of Physical Chemistry C, 2008, 112, 1446-1454.
18)Xing, Y.; Liu, Z.; Suib,S.L.Inorganic synthesis for the stabilization of nanoparticles: Application to Cu/Al2O3Nanocomposite MaterialsChemistry of Materials, 2007, 19,4820-4826.
19) Xing, Y.; Liu, Z.; Couttenye, R.A.; Willis, W.S.; Suib, S.L.; Fanson, P.T.; Hirata, H.; Ibe,M.Generation of hydrogen and light hydrocarbons for automotive exhaust gas purification: Conversion of n-hexane in a PACT (plasma and catalysis integrated technologies) reactorJournal of Catalysis, 2007, 250, 67-74.
GrantedPatents(授权专利)
·Method for catalytic conversion of synthetic gas, China Patent No. ZL6.3, Grant Publication No. CNB, Grant Date 2017.6.30.
·A cryptomelane molecular sieve macroscopic three-dimensional foam material and its preparation method, China Patent No. ZL201510554029.9, Grant Publication No. CNB, Grant Date 2017.8.29.
·Zeolite catalysts for the transalkylation of benzene and C9+ aromatics, China Patent No. ZL**.0, Grant Publication No. CN**C, Grant Date 2005.5.4.
·The transalkylation method of benzene and C9+ aromatic hydrocarbons, China Patent No. ZL**.2, Grant Publication No. CN**C, Grant Date 2005.3.23.
·The transalkylation method of benzene and C9 arene, China Patent No. ZL**.5, Grant Publication No. CN**C, Grant Date 2005.8.24.
·Process for removing organic amine from βzeolite, China Patent No. ZL**.9, Grant Publication No. CN **C, Grant Date 2005.5.4.
·Manufacture of beta-zeolites, China Patent No. ZL**.X, Grant Publication No. CN **C, Grant Date 2004.2.25.
Awards & Honors(获奖与荣誉)
(1)2013.12,“Deactivation of Pt/F-KL Zeolite-type Naphtha Reforming Catalysts: in-situ IR and on-line Mass Spectrometry Studies of Fluorine Loss”,河南省第二届自然科学学术奖——河南省自然科学学术论文一等奖,第一。
(2)2017.05,“锂电正极材料的碳膜均匀化研究”,河南省教育厅科技成果一等奖,主持,第一。
(3)2017.05,“高密度的纳米级磷酸亚铁锂动力电池材料研究”,河南省教育厅科技成果二等奖,主持,第一。
(4)2019.08,“创新创业环境下本科生毕业论文指导的探索与体会”,2019年度河南省教育科学研究成果二等奖,第二。
(5)2017.05,被评为河南省高等学校青年骨干教师,发证单位:河南省教育厅。
Affiliations(学术兼职)
(1)省青科协理事;
(2)美国Sigma Xi、Phi Kappa Phi、ACS等学会会员。
3.在研的项目
(1)国家自然科学基金面上项目(NSFC #**),“高烯烷比、低甲烷、耐热且组成稳定的FTO用纳米复合催化材料及其作用机理”
(2)河南省高等学校重点科研项目资助计划(20A150044),“煤基合成气制低碳烯烃用助剂/载体协同催化体系”
(3)省属高校基本科研业务费专项资金项目(19KYYWF0402),“CO加氢直接制取低碳烯烃用铁系催化剂”
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